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Adsorption and molecular siting of CO(2), water, and other gases in the superhydrophobic, flexible pores of FMOF-1 from experiment and simulation
FMOF-1 is a flexible, superhydrophobic metal–organic framework with a network of channels and side pockets decorated with –CF(3) groups. CO(2) adsorption isotherms measured between 278 and 313 K and up to 55 bar reveal a maximum uptake of ca. 6.16 mol kg(–1) (11.0 mol L(–1)) and unusual isotherm sha...
Autores principales: | , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433493/ https://www.ncbi.nlm.nih.gov/pubmed/28553541 http://dx.doi.org/10.1039/c7sc00278e |