Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis

Solvent effects in a series of Fe(iii) spin crossover (SCO) complexes [Fe(qsal-I)(2)]OTf·sol (sol = MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is abrupt in 1 (following MeOH loss) and 2, gradual for 3 (T (1/2) = 199 K) and 4 (T (1/2) = 251 K) and incomplete, even up...

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Detalles Bibliográficos
Autores principales: Phonsri, Wasinee, Harding, Phimphaka, Liu, Lujia, Telfer, Shane G., Murray, Keith S., Moubaraki, Boujemaa, Ross, Tamsyn M., Jameson, Guy N. L., Harding, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433504/
https://www.ncbi.nlm.nih.gov/pubmed/28553537
http://dx.doi.org/10.1039/c6sc05317c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433504/
https://www.ncbi.nlm.nih.gov/pubmed/28553537
http://dx.doi.org/10.1039/c6sc05317c

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