Cargando…

Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis

Solvent effects in a series of Fe(iii) spin crossover (SCO) complexes [Fe(qsal-I)(2)]OTf·sol (sol = MeOH 1, EtOH 2, n-PrOH 3, i-PrOH 4, acetone 5 and MeCN 6) are explored. SCO is abrupt in 1 (following MeOH loss) and 2, gradual for 3 (T (1/2) = 199 K) and 4 (T (1/2) = 251 K) and incomplete, even up...

Descripción completa

Detalles Bibliográficos
Autores principales:	Phonsri, Wasinee, Harding, Phimphaka, Liu, Lujia, Telfer, Shane G., Murray, Keith S., Moubaraki, Boujemaa, Ross, Tamsyn M., Jameson, Guy N. L., Harding, David J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433504/ https://www.ncbi.nlm.nih.gov/pubmed/28553537 http://dx.doi.org/10.1039/c6sc05317c

Ejemplares similares

Bidirectional photoswitchability in an iron(iii) spin crossover complex: symmetry-breaking and solvent effects
por: Díaz-Torres, Raúl, et al.
Publicado: (2023)

Room temperature conductance switching in a molecular iron(iii) spin crossover junction
por: Karuppannan, Senthil Kumar, et al.
Publicado: (2020)

Iron(II) Spin Crossover Complexes with 4,4′-Dipyridylethyne—Crystal Structures and Spin Crossover with Hysteresis
por: Dankhoff, Katja, et al.
Publicado: (2020)

Solvent-Induced Polymorphism of Iron(II) Spin Crossover Complexes
por: Šalitroš, Ivan, et al.
Publicado: (2016)

Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate
por: Harding, David J., et al.
Publicado: (2008)

(8-Aminoquinoline-κ(2) N,N′)bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)cobalt(II)
por: Harding, David J., et al.
Publicado: (2012)

[Tris(3,5-diphenylpyrazolyl)hydroborato]nickel(II) bromide
por: Harding, David J., et al.
Publicado: (2009)

(Di-2-pyridylamine-κ(2) N,N′)[hydrotris(3,5-diphenylpyrazol-1-yl-κN (2))borato]nickel(II) bromide dichloromethane monosolvate
por: Harding, David J., et al.
Publicado: (2011)

Tris(5-methyl-3-phenyl-1H-pyrazol-1-yl)methane
por: Harding, David J., et al.
Publicado: (2008)

Thermal hysteresis of stress and strain in spin-crossover@polymer composites: towards a rational design of actuator devices
por: Angulo-Cervera, José Elias, et al.
Publicado: (2022)

[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ(2) N,N′]bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)nickel(II)
por: Harding, Phimphaka, et al.
Publicado: (2011)

[(4-Bromophenyl)(2-pyridylmethylidene)amine-κ(2) N,N′]bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-κ(2) O,O′)cobalt(II)
por: Harding, Phimphaka, et al.
Publicado: (2010)

Spin-State Patterning in an Iron(II) Tripodal Spin-Crossover Complex
por: Li, Li, et al.
Publicado: (2017)

Reduction of Hysteresis in Hybrid Perovskite Transistors by Solvent-Controlled Growth
por: Haque, Farjana, et al.
Publicado: (2021)

Hysteresis data of planar perovskite solar cells fabricated with different solvents
por: Seo, You-Hyun, et al.
Publicado: (2017)

Seismological expression of the iron spin crossover in ferropericlase in the Earth’s lower mantle
por: Shephard, Grace E., et al.
Publicado: (2021)

Preparation and physicochemical characterization of sildenafil cocrystals
por: Sawatdee, Somchai, et al.
Publicado: (2021)

Exceptional points in classical spin dynamics
por: Galda, Alexey, et al.
Publicado: (2019)

Modulated self-reversed magnetic hysteresis in iron oxides
por: Ma, Ji, et al.
Publicado: (2017)

Reversible quantitative guest sensing via spin crossover of an iron(ii) triazole
por: Miller, Reece G., et al.
Publicado: (2016)

Iron(II) Mediated Supramolecular Architectures with Schiff Bases and Their Spin-Crossover Properties
por: Tesfaye, Dawit, et al.
Publicado: (2023)

Synthesis and characterization of highly diluted polyanionic iron(II) spin crossover systems
por: Moneo-Corcuera, Andrea, et al.
Publicado: (2023)

Spin-crossover and high-spin iron(ii) complexes as chemical shift (19)F magnetic resonance thermometers
por: Thorarinsdottir, Agnes E., et al.
Publicado: (2017)

Emergent superconductivity in an iron-based honeycomb lattice initiated by pressure-driven spin-crossover
por: Wang, Yonggang, et al.
Publicado: (2018)

A Mononuclear Iron(II) Spin-Crossover Molecule Decorated by Photochromic Azobenzene Group
por: Qiu, Jiang-Zhen, et al.
Publicado: (2022)

Near‐Room‐Temperature Magnetoelectric Coupling via Spin Crossover in an Iron(II) Complex
por: Owczarek, Magdalena, et al.
Publicado: (2022)

Hybrid spin-crossover nanostructures
por: Quintero, Carlos M, et al.
Publicado: (2014)

Electronic Control of Spin-Crossover Properties in Four-Coordinate Bis(formazanate) Iron(II) Complexes
por: Milocco, Francesca, et al.
Publicado: (2020)

Chiral Resolution of Spin‐Crossover Active Iron(II) [2x2] Grid Complexes
por: Suryadevara, Nithin, et al.
Publicado: (2021)

Corneal Hysteresis in Thais and Variation of Corneal Hysteresis in Glaucoma
por: Rojananuangnit, Kulawan
Publicado: (2021)

The absence of crossovers on chromosome 4 in Drosophila melanogaster: Imperfection or interesting exception?
por: Hartmann, Michaelyn A., et al.
Publicado: (2017)

Unravelling the chemical design of spin-crossover nanoparticles based on iron(ii)–triazole coordination polymers: towards a control of the spin transition
por: Giménez-Marqués, Mónica, et al.
Publicado: (2015)

Systems with hysteresis
por: Krasnosel’skiǐ, Mark A, et al.
Publicado: (1989)

Magnetic hysteresis
por: Della Torre, Edward
Publicado: (1999)

Magnetic Hysteresis
por: Della Torre, Edward
Publicado: (2000)

Hysteresis machines
por: Sharma, Narendra Dutt, et al.
Publicado: (2003)

The science of hysteresis
por: Bertotti, G, et al.
Publicado: (2005)

Dynamics of Spin Crossover Molecular Complexes
por: Ekanayaka, Thilini K., et al.
Publicado: (2022)

Magnetism, Conductivity and Spin-Spin Interactions in Layered Hybrid Structure of Anionic Radicals [Ni(dmit)(2)] Alternated by Iron(III) Spin-Crossover Complex [Fe(III)(3-OMe-Sal(2)trien)] and Ferric Moiety Precursors
por: Shvachko, Yuri N., et al.
Publicado: (2020)

Manipulating charge transfer excited state relaxation and spin crossover in iron coordination complexes with ligand substitution
por: Zhang, Wenkai, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_gamqg15aqbc9vag8befj63auvu