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Spectroscopic observation of two-center three-electron bonded (hemi-bonded) structures of (H(2)S)(n) (+) clusters in the gas phase

A two-center three-electron 2c–3e bond (hemi-bond) is a non-classical chemical bond, and its existence has been supposed in radical cation clusters with lone pairs. Though the nature of the hemi-bond and its role in the reactivity of radical cations have attracted great interest, spectroscopic obser...

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Detalles Bibliográficos
Autores principales: Wang, Dandan, Fujii, Asuka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433515/
https://www.ncbi.nlm.nih.gov/pubmed/28553502
http://dx.doi.org/10.1039/c6sc05361k