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Spectroscopic observation of two-center three-electron bonded (hemi-bonded) structures of (H(2)S)(n) (+) clusters in the gas phase
A two-center three-electron 2c–3e bond (hemi-bond) is a non-classical chemical bond, and its existence has been supposed in radical cation clusters with lone pairs. Though the nature of the hemi-bond and its role in the reactivity of radical cations have attracted great interest, spectroscopic obser...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5433515/ https://www.ncbi.nlm.nih.gov/pubmed/28553502 http://dx.doi.org/10.1039/c6sc05361k |