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Pentavalent lanthanide nitride-oxides: NPrO and NPrO(–) complexes with N[triple bond, length as m-dash]Pr triple bonds
The neutral molecule NPrO and its anion NPrO(–) are produced via co-condensation of laser-ablated praseodymium atoms with nitric oxide in a solid neon matrix. Combined infrared spectroscopy and state-of-the-art quantum chemical calculations confirm that both species are pentavalent praseodymium nitr...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5434915/ https://www.ncbi.nlm.nih.gov/pubmed/28580119 http://dx.doi.org/10.1039/c7sc00710h |