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Pentavalent lanthanide nitride-oxides: NPrO and NPrO(–) complexes with N[triple bond, length as m-dash]Pr triple bonds

The neutral molecule NPrO and its anion NPrO(–) are produced via co-condensation of laser-ablated praseodymium atoms with nitric oxide in a solid neon matrix. Combined infrared spectroscopy and state-of-the-art quantum chemical calculations confirm that both species are pentavalent praseodymium nitr...

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Detalles Bibliográficos
Autores principales: Hu, Shu-Xian, Jian, Jiwen, Su, Jing, Wu, Xuan, Li, Jun, Zhou, Mingfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5434915/
https://www.ncbi.nlm.nih.gov/pubmed/28580119
http://dx.doi.org/10.1039/c7sc00710h