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Phosphasalen Indium Complexes Showing High Rates and Isoselectivities in rac‐Lactide Polymerizations

Polylactide (PLA) is the leading bioderived polymer produced commercially by the metal‐catalyzed ring‐opening polymerization of lactide. Control over tacticity to produce stereoblock PLA, from rac‐lactide improves thermal properties but is an outstanding challenge. Here, phosphasalen indium catalyst...

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Detalles Bibliográficos
Autores principales: Myers, Dominic, White, Andrew J. P., Forsyth, Craig M., Bown, Mark, Williams, Charlotte K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5434947/
https://www.ncbi.nlm.nih.gov/pubmed/28378455
http://dx.doi.org/10.1002/anie.201701745