Using signal amplification by reversible exchange (SABRE) to hyperpolarise (119)Sn and (29)Si NMR nuclei

The hyperpolarisation of the (119)Sn and (29)Si nuclei in 5-(tributylstannyl)pyrimidine (A (Sn)) and 5-(trimethylsilyl)pyrimidine (B (Si)) is achieved through their reaction with [IrCl(COD)(IMes)] (1a) or [IrCl(COD)(SIMes)] (1b) and parahydrogen via the SABRE process. 1a exhibits superior activity i...

Descripción completa

Detalles Bibliográficos
Autores principales: Olaru, Alexandra M., Burt, Alister, Rayner, Peter J., Hart, Sam J., Whitwood, Adrian C., Green, Gary G. R., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5436037/
https://www.ncbi.nlm.nih.gov/pubmed/27904890
http://dx.doi.org/10.1039/c6cc07109k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5436037/
https://www.ncbi.nlm.nih.gov/pubmed/27904890
http://dx.doi.org/10.1039/c6cc07109k

Ejemplares similares