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Using signal amplification by reversible exchange (SABRE) to hyperpolarise (119)Sn and (29)Si NMR nuclei

The hyperpolarisation of the (119)Sn and (29)Si nuclei in 5-(tributylstannyl)pyrimidine (A (Sn)) and 5-(trimethylsilyl)pyrimidine (B (Si)) is achieved through their reaction with [IrCl(COD)(IMes)] (1a) or [IrCl(COD)(SIMes)] (1b) and parahydrogen via the SABRE process. 1a exhibits superior activity i...

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Detalles Bibliográficos
Autores principales:	Olaru, Alexandra M., Burt, Alister, Rayner, Peter J., Hart, Sam J., Whitwood, Adrian C., Green, Gary G. R., Duckett, Simon B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5436037/ https://www.ncbi.nlm.nih.gov/pubmed/27904890 http://dx.doi.org/10.1039/c6cc07109k

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