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Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis–Hillman reaction

En route to a photoswitchable interlocked catalyst we have proved the ability of thiodiglycolamide to act as a template in the formation of hydrogen-bonded [2]rotaxanes. X-ray diffraction studies reveal the shielding of the sulfide atom by the macrocycle. A series of molecular shuttles are described...

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Detalles Bibliográficos
Autores principales: Martinez-Cuezva, Alberto, Saura-Sanmartin, Adrian, Nicolas-Garcia, Tomas, Navarro, Cristian, Orenes, Raul-Angel, Alajarin, Mateo, Berna, Jose
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5436546/
https://www.ncbi.nlm.nih.gov/pubmed/28580109
http://dx.doi.org/10.1039/c7sc00724h