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Mild, visible light-mediated decarboxylation of aryl carboxylic acids to access aryl radicals

Herein we present the first example of aryl radical formation via the visible light-mediated decarboxylation of aryl carboxylic acids using photoredox catalysis. This method constitutes a mild protocol for the decarboxylation of cheap and abundant aryl carboxylic acids and tolerates both electron-ri...

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Detalles Bibliográficos
Autores principales: Candish, L., Freitag, M., Gensch, T., Glorius, F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5437376/
https://www.ncbi.nlm.nih.gov/pubmed/28580100
http://dx.doi.org/10.1039/c6sc05533h