Controlling superstructural ordering in the clathrate-I Ba(8)M(16)P(30) (M = Cu, Zn) through the formation of metal–metal bonds

Order–disorder–order phase transitions in the clathrate-I Ba(8)Cu(16)P(30) were induced and controlled by aliovalent substitutions of Zn into the framework. Unaltered Ba(8)Cu(16)P(30) crystallizes in an ordered orthorhombic (Pbcn) clathrate-I superstructure that maintains complete segregation of met...

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Detalles Bibliográficos
Autores principales: Dolyniuk, J., Whitfield, P. S., Lee, K., Lebedev, O. I., Kovnir, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5437377/
https://www.ncbi.nlm.nih.gov/pubmed/28580103
http://dx.doi.org/10.1039/c7sc00354d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5437377/
https://www.ncbi.nlm.nih.gov/pubmed/28580103
http://dx.doi.org/10.1039/c7sc00354d

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