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Controlling superstructural ordering in the clathrate-I Ba(8)M(16)P(30) (M = Cu, Zn) through the formation of metal–metal bonds

Order–disorder–order phase transitions in the clathrate-I Ba(8)Cu(16)P(30) were induced and controlled by aliovalent substitutions of Zn into the framework. Unaltered Ba(8)Cu(16)P(30) crystallizes in an ordered orthorhombic (Pbcn) clathrate-I superstructure that maintains complete segregation of met...

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Detalles Bibliográficos
Autores principales:	Dolyniuk, J., Whitfield, P. S., Lee, K., Lebedev, O. I., Kovnir, K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5437377/ https://www.ncbi.nlm.nih.gov/pubmed/28580103 http://dx.doi.org/10.1039/c7sc00354d

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