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(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles
Although BH(3) simply coordinates the endocyclic P of (phospholidino)phosphaketene 1(Dipp) , the bulkier B(C(6)F(5))(3) gives rise to a zwitterionic diphosphirenium, which is a novel type of 2π-electron aromatic system as shown by the calculated NICS values. While the reaction of 1(Dipp) with Na[PCO...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5437511/ https://www.ncbi.nlm.nih.gov/pubmed/28580107 http://dx.doi.org/10.1039/c7sc00300e |