Reactivity of hydride bridges in a high-spin [Fe(3)(μ-H)(3)](3+) cluster: reversible H(2)/CO exchange and Fe–H/B–F bond metathesis

The triiron trihydride complex Fe(3)H(3) L (1) [where L (3–) is a tris(β-diketiminate)cyclophanate] reacts with CO and with BF(3)·OEt(2) to afford (Fe(I)CO)(2)Fe(II)(μ(3)-H)L (2) and Fe(3)F(3) L (3), respectively. Variable-temperature and applied-field Mössbauer spectroscopy support the assignment o...

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Detalles Bibliográficos
Autores principales: Anderton, Kevin J., Knight, Brian J., Rheingold, Arnold L., Abboud, Khalil A., García-Serres, Ricardo, Murray, Leslie J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5443887/
https://www.ncbi.nlm.nih.gov/pubmed/28603601
http://dx.doi.org/10.1039/c6sc05583d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5443887/
https://www.ncbi.nlm.nih.gov/pubmed/28603601
http://dx.doi.org/10.1039/c6sc05583d

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