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Synthesis of Aryliron Complexes [CpFe(CO)(2)Ar] by Palladium-Catalyzed Reactions of [CpFe(CO)(2)I] with Arylzinc, -Boron, or -Indium Reagents

Transmetalation between [CpFe(CO)(2)I] and arylzinc iodide-lithium chloride complexes proceeds in the presence of catalytic amounts of palladium acetate and N,N,N’,N’-tetramethyl-1,2-cyclohexanediamine to yield the corresponding aryliron complexes [CpFe(CO)(2)Ar]. Phenylation of [CpFe(CO)(2)I] also...

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Detalles Bibliográficos
Autores principales: Yasuda, Shigeo, Asada, Yoshihiro, Yorimitsu, Hideki, Oshima, Koichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5445742/
http://dx.doi.org/10.3390/ma2030978