Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase

The monoesters of carbonic acid are deemed to be unstable and decompose to alcohol and carbon dioxide. In spite of this, we here report the isolation of the elusive carbonic acid monoethyl ester (CAEE) as a pure solid from ethanolic solutions of potassium bicarbonate. The hemiester is surprisingly s...

Descripción completa

Detalles Bibliográficos
Autores principales: Bernard, Jürgen, Köck, Eva-Maria, Huber, Roland G., Liedl, Klaus R., Call, Ludwig, Schlögl, Robert, Grothe, Hinrich, Loerting, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450006/
https://www.ncbi.nlm.nih.gov/pubmed/28603608
http://dx.doi.org/10.1039/c7ra02792c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450006/
https://www.ncbi.nlm.nih.gov/pubmed/28603608
http://dx.doi.org/10.1039/c7ra02792c

Ejemplares similares