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Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase
The monoesters of carbonic acid are deemed to be unstable and decompose to alcohol and carbon dioxide. In spite of this, we here report the isolation of the elusive carbonic acid monoethyl ester (CAEE) as a pure solid from ethanolic solutions of potassium bicarbonate. The hemiester is surprisingly s...
Autores principales: | Bernard, Jürgen, Köck, Eva-Maria, Huber, Roland G., Liedl, Klaus R., Call, Ludwig, Schlögl, Robert, Grothe, Hinrich, Loerting, Thomas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450006/ https://www.ncbi.nlm.nih.gov/pubmed/28603608 http://dx.doi.org/10.1039/c7ra02792c |
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