Ferrocenyl chiral bisphosphorus ligands for highly enantioselective asymmetric hydrogenation via noncovalent ion pair interaction

A new class of ferrocenyl chiral bisphosphorus ligand, Wudaphos, was developed, and exhibits excellent ee and activity (ee up to 99%, TON up to 20 000) for the asymmetric hydrogenation of both 2-aryl and 2-alkyl acrylic acids through ion pair noncovalent interaction under base free and mild reaction...

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Detalles Bibliográficos
Autores principales: Chen, Caiyou, Wang, Heng, Zhang, Zhefan, Jin, Shicheng, Wen, Songwei, Ji, Jianjian, Chung, Lung Wa, Dong, Xiu-Qin, Zhang, Xumu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450526/
https://www.ncbi.nlm.nih.gov/pubmed/28567257
http://dx.doi.org/10.1039/c6sc01845a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450526/
https://www.ncbi.nlm.nih.gov/pubmed/28567257
http://dx.doi.org/10.1039/c6sc01845a

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