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Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S(3)˙(–)

Cofacial bimetallic tin(ii) ([Sn(2)(mBDCA-5t)](2–), 1) and lead(ii) ([Pb(2)(mBDCA-5t)](2–), 2) complexes have been prepared by hexadeprotonation of hexacarboxamide cryptand mBDCA-5t-H(6) together with double Sn(ii) or Pb(ii) insertion. Reaction of 1 with elemental sulfur or selenium generates di-tin...

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Detalles Bibliográficos
Autores principales: Stauber, Julia M., Müller, Peter, Dai, Yizhe, Wu, Gang, Nocera, Daniel G., Cummins, Christopher C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450590/
https://www.ncbi.nlm.nih.gov/pubmed/28567264
http://dx.doi.org/10.1039/c6sc01754a