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Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S(3)˙(–)
Cofacial bimetallic tin(ii) ([Sn(2)(mBDCA-5t)](2–), 1) and lead(ii) ([Pb(2)(mBDCA-5t)](2–), 2) complexes have been prepared by hexadeprotonation of hexacarboxamide cryptand mBDCA-5t-H(6) together with double Sn(ii) or Pb(ii) insertion. Reaction of 1 with elemental sulfur or selenium generates di-tin...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5450590/ https://www.ncbi.nlm.nih.gov/pubmed/28567264 http://dx.doi.org/10.1039/c6sc01754a |