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Au(iii)-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis
Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C–O and C–N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C–O an...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452266/ https://www.ncbi.nlm.nih.gov/pubmed/28572904 http://dx.doi.org/10.1039/c6sc03699f |