Chemoselective oxidation of aryl organoboron systems enabled by boronic acid-selective phase transfer

We report the direct chemoselective Brown-type oxidation of aryl organoboron systems containing two oxidizable boron groups. Basic biphasic reaction conditions enable selective formation and phase transfer of a boronic acid trihydroxyboronate in the presence of boronic acid pinacol (BPin) esters, wh...

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Detalles Bibliográficos
Autores principales: Molloy, John J., Clohessy, Thomas A., Irving, Craig, Anderson, Niall A., Lloyd-Jones, Guy C., Watson, Allan J. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452267/
https://www.ncbi.nlm.nih.gov/pubmed/28572912
http://dx.doi.org/10.1039/c6sc04014d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452267/
https://www.ncbi.nlm.nih.gov/pubmed/28572912
http://dx.doi.org/10.1039/c6sc04014d

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