Probing Transient Valence Orbital Changes with Picosecond Valence-to-Core X-ray Emission Spectroscopy

[Image: see text] We probe the dynamics of valence electrons in photoexcited [Fe(terpy)(2)](2+) in solution to gain deeper insight into the Fe–ligand bond changes. We use hard X-ray emission spectroscopy (XES), which combines element specificity and high penetration with sensitivity to orbital struc...

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Detalles Bibliográficos
Autores principales: March, Anne Marie, Assefa, Tadesse A., Boemer, Christina, Bressler, Christian, Britz, Alexander, Diez, Michael, Doumy, Gilles, Galler, Andreas, Harder, Manuel, Khakhulin, Dmitry, Németh, Zoltán, Pápai, Mátyás, Schulz, Sebastian, Southworth, Stephen H., Yavaş, Hasan, Young, Linda, Gawelda, Wojciech, Vankó, György
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453616/
https://www.ncbi.nlm.nih.gov/pubmed/28580048
http://dx.doi.org/10.1021/acs.jpcc.6b12940

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453616/
https://www.ncbi.nlm.nih.gov/pubmed/28580048
http://dx.doi.org/10.1021/acs.jpcc.6b12940

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