Binary Alkali-Metal Silicon Clathrates by Spark Plasma Sintering: Preparation and Characterization

The binary intermetallic clathrates K(8-x)Si(46) (x = 0.4; 1.2), Rb(6.2)Si(46), Rb(11.5)Si(136) and Cs(7.8)Si(136) were prepared from M(4)Si(4) (M = K, Rb, Cs) precursors by spark-plasma route (SPS) and structurally characterized by Rietveld refinement of PXRD data. The clathrate-II phase Rb(11.5)Si...

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Detalles Bibliográficos
Autores principales: Veremchuk, Igor, Beekman, Matt, Antonyshyn, Iryna, Schnelle, Walter, Baitinger, Michael, Nolas, George S., Grin, Yuri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456916/
https://www.ncbi.nlm.nih.gov/pubmed/28773710
http://dx.doi.org/10.3390/ma9070593

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456916/
https://www.ncbi.nlm.nih.gov/pubmed/28773710
http://dx.doi.org/10.3390/ma9070593

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