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Binary Alkali-Metal Silicon Clathrates by Spark Plasma Sintering: Preparation and Characterization

The binary intermetallic clathrates K(8-x)Si(46) (x = 0.4; 1.2), Rb(6.2)Si(46), Rb(11.5)Si(136) and Cs(7.8)Si(136) were prepared from M(4)Si(4) (M = K, Rb, Cs) precursors by spark-plasma route (SPS) and structurally characterized by Rietveld refinement of PXRD data. The clathrate-II phase Rb(11.5)Si...

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Detalles Bibliográficos
Autores principales:	Veremchuk, Igor, Beekman, Matt, Antonyshyn, Iryna, Schnelle, Walter, Baitinger, Michael, Nolas, George S., Grin, Yuri
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2016
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456916/ https://www.ncbi.nlm.nih.gov/pubmed/28773710 http://dx.doi.org/10.3390/ma9070593

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