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Carbon dioxide binding at a Ni/Fe center: synthesis and characterization of Ni(η(1)-CO(2)-κC) and Ni-μ-CO(2)-κC:κ(2) O,O′-Fe
The degree of CO(2) activation can be tuned by incorporating a distinct electronic coordination environment at the nickel center. A mononuclear nickel carboxylate species (Ni–CO(2), 3) and a dinuclear nickel–iron carboxylate species (Ni–CO(2)–Fe, 5) were prepared. The structure of 3 reveals a rare η...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458731/ https://www.ncbi.nlm.nih.gov/pubmed/28616135 http://dx.doi.org/10.1039/c6sc03450k |