Infrared spectroscopy of the nitrogenase MoFe protein under electrochemical control: potential-triggered CO binding

We demonstrate electrochemical control of the nitrogenase MoFe protein, in the absence of Fe protein or ATP, using europium(iii/ii) polyaminocarboxylate complexes as electron transfer mediators. This allows the potential dependence of proton reduction and inhibitor (CO) binding to the active site Fe...

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Detalles Bibliográficos
Autores principales: Paengnakorn, P., Ash, P. A., Shaw, S., Danyal, K., Chen, T., Dean, D. R., Seefeldt, L. C., Vincent, K. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460594/
https://www.ncbi.nlm.nih.gov/pubmed/28616146
http://dx.doi.org/10.1039/c6sc02860h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460594/
https://www.ncbi.nlm.nih.gov/pubmed/28616146
http://dx.doi.org/10.1039/c6sc02860h

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