Stereodivergent, Diels–Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application

Chiral α,β-unsaturated acylammonium salts are novel dienophiles enabling enantioselective Diels–Alder-lactonization (DAL) organocascades leading to cis- and trans-fused, bicyclic γ- and δ-lactones from readily prepared dienes, commodity acid chlorides, and a chiral isothiourea organocatalyst under m...

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Detalles Bibliográficos
Autores principales: Abbasov, Mikail E., Hudson, Brandi M., Tantillo, Dean J., Romo, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460596/
https://www.ncbi.nlm.nih.gov/pubmed/28616147
http://dx.doi.org/10.1039/c6sc04273b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460596/
https://www.ncbi.nlm.nih.gov/pubmed/28616147
http://dx.doi.org/10.1039/c6sc04273b

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