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Mechanistic study of the rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide
A detailed mechanism of the Rh(i)-catalyzed carboxylation of simple aromatic compounds via C–H bond activation was investigated. Kinetic studies with model compounds of the postulated key intermediates revealed that 14-electron complexes, RhMe(dcype) and RhPh(dcype), participated in the C–H bond act...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460598/ https://www.ncbi.nlm.nih.gov/pubmed/28616144 http://dx.doi.org/10.1039/c6sc03838g |