A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO(2)/ethylene coupling

A family of cis-macrocyclic diphosphines was prepared in just three steps from white phosphorus and commercial materials using a modular synthetic approach. Alkylation of bicyclic diphosphane 3,4,8,9-tetramethyl-1,6-diphosphabicyclo(4.4.0)deca-3,8-diene, or P(2)(dmb)(2), produced phosphino-phosphoni...

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Detalles Bibliográficos
Autores principales: Knopf, Ioana, Tofan, Daniel, Beetstra, Dirk, Al-Nezari, Abdulaziz, Al-Bahily, Khalid, Cummins, Christopher C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460601/
https://www.ncbi.nlm.nih.gov/pubmed/28616145
http://dx.doi.org/10.1039/c6sc03614g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5460601/
https://www.ncbi.nlm.nih.gov/pubmed/28616145
http://dx.doi.org/10.1039/c6sc03614g

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