Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes

The enantioselective silylation of racemic alcohols, where one enantiomer reacts faster than the other, is an alternative approach to established enzymatic and non-enzymatic acylation techniques. The existing art is either limited to structurally biased alcohols or requires elaborate catalysts. Simp...

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Detalles Bibliográficos
Autores principales: Dong, Xichang, Weickgenannt, Andreas, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461486/
https://www.ncbi.nlm.nih.gov/pubmed/28569754
http://dx.doi.org/10.1038/ncomms15547

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461486/
https://www.ncbi.nlm.nih.gov/pubmed/28569754
http://dx.doi.org/10.1038/ncomms15547

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