Cargando…

Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes

The enantioselective silylation of racemic alcohols, where one enantiomer reacts faster than the other, is an alternative approach to established enzymatic and non-enzymatic acylation techniques. The existing art is either limited to structurally biased alcohols or requires elaborate catalysts. Simp...

Descripción completa

Detalles Bibliográficos
Autores principales:	Dong, Xichang, Weickgenannt, Andreas, Oestreich, Martin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2017
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461486/ https://www.ncbi.nlm.nih.gov/pubmed/28569754 http://dx.doi.org/10.1038/ncomms15547

Ejemplares similares

Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
por: Nagata, Tatsuki, et al.
Publicado: (2019)

A Cu‐Catalysed Radical Cross‐Dehydrogenative Coupling Approach to Acridanes and Related Heterocycles
por: Hurst, Timothy E., et al.
Publicado: (2017)

Reductive Deamination with Hydrosilanes Catalyzed by B(C(6)F(5))(3)
por: Fang, Huaquan, et al.
Publicado: (2020)

Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition‐Metal Catalysts
por: Seliger, Jan, et al.
Publicado: (2020)

Cross dehydrogenative C–O coupling catalysed by a catenane-coordinated copper(i)
por: Zhu, Lihui, et al.
Publicado: (2020)

Computational mechanistic studies of ruthenium catalysed methanol dehydrogenation
por: de Zwart, Felix J., et al.
Publicado: (2022)

Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration
por: He, Tao, et al.
Publicado: (2020)

Manganese catalysed dehydrogenative synthesis of polyureas from diformamide and diamines
por: McLuskie, Angus, et al.
Publicado: (2023)

Gas Phase Hydrogenation of Furaldehydes via Coupling with Alcohol Dehydrogenation over Ceria Supported Au-Cu
por: Pischetola, Chiara, et al.
Publicado: (2018)

Direct synthesis of amides and imines by dehydrogenative homo or cross-coupling of amines and alcohols catalyzed by Cu-MOF
por: Anbardan, Soheil Zamani, et al.
Publicado: (2021)

One out of Four: Kinetic Resolution of Stereoisomeric Mixtures of Secondary Alcohols with a Quaternary Carbon Atom in the β-Position by Cu–H-Catalyzed Enantioselective Silylation
por: Papadopulu, Zaneta, et al.
Publicado: (2021)

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones
por: Romero, R. Martin, et al.
Publicado: (2022)

Defunctionalisation catalysed by boron Lewis acids
por: Fang, Huaquan, et al.
Publicado: (2020)

Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering
por: Hu, Huayou, et al.
Publicado: (2020)

Regioselective hydroesterification of alkenes and alkenylphenols utilizing CO(2) and hydrosilane
por: Wang, Meng-Meng, et al.
Publicado: (2023)

Heterogeneously Catalysed Oxidative Dehydrogenation of Menthol in a Fixed‐Bed Reactor in the Gas Phase
por: Kulik, Anna, et al.
Publicado: (2019)

Isothiourea‐Catalysed Acylative Kinetic Resolution of Aryl–Alkenyl (sp(2) vs. sp(2)) Substituted Secondary Alcohols
por: Musolino, Stefania F., et al.
Publicado: (2016)

Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes
por: He, Tao, et al.
Publicado: (2020)

Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp(3) carbons
por: Wu, Xuesong, et al.
Publicado: (2015)

Acid-promoted iron-catalysed dehydrogenative [4 + 2] cycloaddition for the synthesis of quinolines under air
por: Yang, Jinfei, et al.
Publicado: (2018)

Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization
por: Asgari, Parham, et al.
Publicado: (2019)

Cross-dehydrogenative coupling and oxidative-amination reactions of ethers and alcohols with aromatics and heteroaromatics
por: Lakshman, Mahesh K., et al.
Publicado: (2017)

Versatile Manganese Catalysis for the Synthesis of Poly(silylether)s from Diols and Dicarbonyls with Hydrosilanes
por: Vijjamarri, Srikanth, et al.
Publicado: (2017)

Unprecedent formation of methylsilylcarbonates from iridium-catalyzed reduction of CO(2) with hydrosilanes
por: Guzmán, Jefferson, et al.
Publicado: (2020)

Lipase‐Catalysed Enzymatic Kinetic Resolution of Aromatic Morita‐Baylis‐Hillman Derivatives by Hydrolysis and Transesterification
por: Mathebula, Nompumelelo P., et al.
Publicado: (2022)

Cross-dehydrogenative N–N couplings
por: Tabey, Alexis, et al.
Publicado: (2021)

Cu‐Catalyzed Cross‐Dehydrogenative ortho‐Aminomethylation of Phenols
por: Yu, Congjun, et al.
Publicado: (2018)

Auto‐Tandem Catalysis: Pd(II)‐Catalysed Dehydrogenation/Oxidative Heck Reaction of Cyclopentane‐1,3‐diones
por: Lamb, Claire J. C., et al.
Publicado: (2017)

Recent advances in liquid hydrosilane-mediated catalytic N-formylation of amines with CO(2)
por: Li, Zhengyi, et al.
Publicado: (2020)

Lipase Catalysed Kinetic Resolution of Racemic 1,2-Diols Containing a Chiral Quaternary Center
por: de Gonzalo, Gonzalo
Publicado: (2018)

Cross-dehydrogenative coupling enables enantioselective access to CF(3)-substituted all-carbon quaternary stereocenters
por: Pan, Xiaoguang, et al.
Publicado: (2020)

Synthesis of N-aryl amines enabled by photocatalytic dehydrogenation
por: Kim, Jungwon, et al.
Publicado: (2020)

Electrochemical Synthesis of Carbazoles by Dehydrogenative Coupling Reaction
por: Kehl, Anton, et al.
Publicado: (2020)

Electrochemical Dehydrogenative Acetalization Protection of Alcohols with Tetrahydrofuran
por: Huang, Raolin, et al.
Publicado: (2021)

Hydrosilane-Modified Poly(2-Hydroxyethyl Methacrylate) Brush as a Nanoadhesive for Efficient Silicone Bonding
por: Nielsen, Stefan Urth, et al.
Publicado: (2019)

Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes
por: Chen, Yi, et al.
Publicado: (2020)

Support stabilized PtCu single-atom alloys for propane dehydrogenation
por: Liu, Xiaohe, et al.
Publicado: (2022)

Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
por: Metsänen, Toni T., et al.
Publicado: (2015)

Direct electrochemical generation of organic carbonates by dehydrogenative coupling
por: Gieshoff, Tile, et al.
Publicado: (2018)

Photocatalytic dehydrogenative C-C coupling of acetonitrile to succinonitrile
por: Zhou, Xian, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_2c8jngth88dr2r55f2qj4j6ece