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Transformations of the FeS Clusters of the Methylthiotransferases MiaB and RimO, Detected by Direct Electrochemistry

[Image: see text] The methylthiotransferases (MTTases) represent a subfamily of the S-adenosylmethionine (AdoMet) radical superfamily of enzymes that catalyze the attachment of a methylthioether (-SCH(3)) moiety on unactivated carbon centers. These enzymes contain two [4Fe-4S] clusters, one of which...

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Detalles Bibliográficos
Autores principales: Maiocco, Stephanie J., Arcinas, Arthur J., Landgraf, Bradley J., Lee, Kyung-Hoon, Booker, Squire J., Elliott, Sean J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5461913/
https://www.ncbi.nlm.nih.gov/pubmed/27598886
http://dx.doi.org/10.1021/acs.biochem.6b00670