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Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds

The synthesis and characterization of the first gold(iii)–arene complexes are described. Well-defined (P,C)-cyclometalated gold(iii)–aryl complexes were prepared and characterized by NMR spectroscopy. These complexes swiftly and cleanly reacted with norbornene and ethylene to provide cationic gold(i...

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Detalles Bibliográficos
Autores principales: Rekhroukh, Feriel, Blons, Charlie, Estévez, Laura, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5472032/
https://www.ncbi.nlm.nih.gov/pubmed/28660067
http://dx.doi.org/10.1039/c7sc00145b