Cargando…
Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds
The synthesis and characterization of the first gold(iii)–arene complexes are described. Well-defined (P,C)-cyclometalated gold(iii)–aryl complexes were prepared and characterized by NMR spectroscopy. These complexes swiftly and cleanly reacted with norbornene and ethylene to provide cationic gold(i...
Autores principales: | Rekhroukh, Feriel, Blons, Charlie, Estévez, Laura, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5472032/ https://www.ncbi.nlm.nih.gov/pubmed/28660067 http://dx.doi.org/10.1039/c7sc00145b |
Ejemplares similares
-
Rational development of catalytic Au(I)/Au(III) arylation involving mild oxidative addition of aryl halides
por: Zeineddine, Abdallah, et al.
Publicado: (2017) -
Cyclometalated gold(iii) complexes: noticeable differences between (N,C) and (P,C) ligands in migratory insertion
por: Serra, Jordi, et al.
Publicado: (2018) -
Ligand-enabled oxidation of gold(i) complexes with o-quinones
por: Szalóki, György, et al.
Publicado: (2022) -
Versatility and adaptative behaviour of the P^N chelating ligand MeDalphos within gold(i) π complexes
por: Navarro, Miquel, et al.
Publicado: (2020) -
Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles
por: Rodriguez, Jessica, et al.
Publicado: (2019)