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[C–H···anion] interactions mediate the templation and anion binding properties of topologically non-trivial metal–organic structures in aqueous solutions

Two synthetic approaches—temperature variation and anion templation—allowed for the selective formation of a [2]catenane ([2]C(4+)) or a trefoil knot (TK(6+)), or for the enhanced formation of a Solomon link (SL(8+)), all from a simple set of starting materials (Zn(ii) acetate, diformylpyridine (DFP...

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Detalles Bibliográficos
Autores principales: Bilbeisi, Rana A., Prakasam, Thirumurugan, Lusi, Matteo, El Khoury, Roberto, Platas-Iglesias, Carlos, Charbonnière, Loïc J., Olsen, John-Carl, Elhabiri, Mourad, Trabolsi, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477011/
https://www.ncbi.nlm.nih.gov/pubmed/28660022
http://dx.doi.org/10.1039/c5sc04246a