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[C–H···anion] interactions mediate the templation and anion binding properties of topologically non-trivial metal–organic structures in aqueous solutions
Two synthetic approaches—temperature variation and anion templation—allowed for the selective formation of a [2]catenane ([2]C(4+)) or a trefoil knot (TK(6+)), or for the enhanced formation of a Solomon link (SL(8+)), all from a simple set of starting materials (Zn(ii) acetate, diformylpyridine (DFP...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477011/ https://www.ncbi.nlm.nih.gov/pubmed/28660022 http://dx.doi.org/10.1039/c5sc04246a |