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Reversible quantitative guest sensing via spin crossover of an iron(ii) triazole

A new phenyl-triazole-pyrazine ligand, 4-p-tolyl-3-(phenyl)-5-(2-pyrazinyl)-1,2,4-triazole (tolpzph), was prepared in order to enforce pyrazine coordination of the iron(ii) centre in the resulting complex, [Fe(II)(tolpzph)(2)(NCS)(2)]·THF (1·THF). Structure determinations carried out on this discret...

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Detalles Bibliográficos
Autores principales: Miller, Reece G., Brooker, Sally
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477032/
https://www.ncbi.nlm.nih.gov/pubmed/28660019
http://dx.doi.org/10.1039/c5sc04583e