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A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds
A highly tunable radical-mediated reaction system for the functionalization of tertiary aliphatic C–H bonds was developed. Reactions of various substrates with the Zhdankin azidoiodane reagent 1, Ru(bpy)(3)Cl(2), and visible light irradiation at room temperature gave C–H azidated or halogenated prod...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477033/ https://www.ncbi.nlm.nih.gov/pubmed/28660040 http://dx.doi.org/10.1039/c5sc04169d |