Cargando…

A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C–H bonds

A highly tunable radical-mediated reaction system for the functionalization of tertiary aliphatic C–H bonds was developed. Reactions of various substrates with the Zhdankin azidoiodane reagent 1, Ru(bpy)(3)Cl(2), and visible light irradiation at room temperature gave C–H azidated or halogenated prod...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Yaxin, Li, Guo-Xing, Yang, Guohui, He, Gang, Chen, Gong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477033/ https://www.ncbi.nlm.nih.gov/pubmed/28660040 http://dx.doi.org/10.1039/c5sc04169d

Ejemplares similares

Visible light C–H amidation of heteroarenes with benzoyl azides
por: Brachet, E., et al.
Publicado: (2015)

Thermodynamics and Spectroscopy of Halogen- and Hydrogen-Bonded Complexes of Haloforms with Aromatic and Aliphatic Amines
por: Adeniyi, Emmanuel, et al.
Publicado: (2022)

Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds
por: Short, Melanie A., et al.
Publicado: (2019)

Enantioselective intramolecular C–H amination of aliphatic azides by dual ruthenium and phosphine catalysis
por: Qin, Jie, et al.
Publicado: (2019)

Visible light-mediated radical fluoromethylation via halogen atom transfer activation of fluoroiodomethane
por: Deneny, Patrick J., et al.
Publicado: (2021)

Shining light on halogen-bonding complexes: a catalyst-free activation mode of carbon–halogen bonds for the generation of carbon-centered radicals
por: Piedra, Helena F., et al.
Publicado: (2023)

Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles
por: Kuijpers, Petrus F., et al.
Publicado: (2017)

Direct nitration and azidation of aliphatic carbons by an iron-dependent halogenase
por: Matthews, Megan L, et al.
Publicado: (2014)

Genetic adaptation of bacteria to halogenated aliphatic compounds.
por: Janssen, D B, et al.
Publicado: (1995)

Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization
por: Sharma, Ankit, et al.
Publicado: (2015)

Influence of aliphatic alcohols on the hepatic response to halogenated olefins.
por: Cornish, H H, et al.
Publicado: (1977)

Sulfonylative and Azidosulfonylative Cyclizations by Visible‐Light‐Photosensitization of Sulfonyl Azides in THF
por: Zhu, Shaoqun, et al.
Publicado: (2017)

Visible light-triggered selective C(sp(2))-H/C(sp(3))-H coupling of benzenes with aliphatic hydrocarbons
por: Li, Qian-Yu, et al.
Publicado: (2023)

Quantification of Noncovalent Interactions in Azide–Pnictogen, –Chalcogen, and –Halogen Contacts
por: Bursch, Markus, et al.
Publicado: (2021)

Visible-Light-Induced Catalytic Selective Halogenation with Photocatalyst
por: Luu, Truong Giang, et al.
Publicado: (2021)

Construction of Benzenesulfonamide Derivatives via Copper and Visible Light-induced Azides and S(O)(2)–H Coupling
por: Liang, Zhipeng, et al.
Publicado: (2022)

The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes
por: Somekh, Miriam, et al.
Publicado: (2020)

Recent application of visible-light induced radicals in C–S bond formation
por: Srivastava, Vishal, et al.
Publicado: (2020)

Direct Arylation of Strong Aliphatic C–H Bonds
por: Perry, Ian B., et al.
Publicado: (2018)

Activation of perfluoroalkyl iodides by anions: extending the scope of halogen bond activation to C(sp(3))–H amidation, C(sp(2))–H iodination, and perfluoroalkylation reactions
por: Wang, Yaxin, et al.
Publicado: (2023)

Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp(3))-H Bond Allylation
por: Zhang, Jing, et al.
Publicado: (2019)

Activation of a Metal‐Halogen Bond by Halogen Bonding
por: Wolf, Julian, et al.
Publicado: (2020)

A Biomolecule-Compatible Visible Light-Induced Azide Reduction from a DNA-Encoded Reaction Discovery System
por: Chen, Yiyun, et al.
Publicado: (2011)

Halogen-Bonding-Mediated Radical Reactions: The Unexpected Behavior of Piperazine-Based Dithiooxamide Ligands in the Presence of Diiodine
por: Rizzato, Silvia, et al.
Publicado: (2023)

Type II halogen···halogen contacts are halogen bonds
por: Metrangolo, Pierangelo, et al.
Publicado: (2013)

Methods for direct C(sp(2))–H bonds azidation
por: Liu, Ying, et al.
Publicado: (2019)

The Halogen Bond
por: Cavallo, Gabriella, et al.
Publicado: (2016)

Iron porphyrin catalysed light driven C–H bond amination and alkene aziridination with organic azides
por: Du, Yi-Dan, et al.
Publicado: (2020)

Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions
por: Svatunek, Dennis, et al.
Publicado: (2018)

Aliphatic Halogenated Hydrocarbons: Report and Analysis of Liver Injury in 60 Patients
por: Teschke, Rolf
Publicado: (2018)

A halogen-bonding-catalyzed Michael addition reaction
por: Gliese, Jan-Philipp, et al.
Publicado: (2017)

Photochemical halogen-bonding assisted generation of vinyl and sulfur-centered radicals: stereoselective catalyst-free C(sp(2))–S bond forming reactions
por: Piedra, Helena F., et al.
Publicado: (2022)

Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C–C Bonds
por: Barata-Vallejo, Sebastián, et al.
Publicado: (2019)

Chemoselective Aliphatic C–H Bond Oxidation Enabled by Polarity Reversal
por: Dantignana, Valeria, et al.
Publicado: (2017)

The Effect of the Reaction pH on Properties of Lead(II) Azide
por: Biegańska, Jolanta
Publicado: (2021)

Intramolecular Csp(3)–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines
por: Wen, Xiaojin, et al.
Publicado: (2020)

The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond
por: Sun, Jiyu, et al.
Publicado: (2023)

Evidence for Halogen Bond Covalency in Acyclic and Interlocked Halogen-Bonding Receptor Anion Recognition
por: Robinson, Sean W., et al.
Publicado: (2014)

Pushing the limits of the hydrogen bond enhanced halogen bond—the case of the C–H hydrogen bond
por: Decato, Daniel A., et al.
Publicado: (2022)

Efficient Light-Induced Phase Transitions in Halogen-Bonded Liquid Crystals
por: Fernandez-Palacio, Francisco, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_o2qoo637lnfp91udss4aiac28f