A complex with nitrogen single, double, and triple bonds to the same chromium atom: synthesis, structure, and reactivity

A nitrogen-based analogue of the Schrock and Clark “yl-ene-yne” complex, W(CBu(t))(CHBu(t))(CH(2)Bu(t))(dmpe), has been prepared. The new complex is the nitrido, imido, amido anion [NCr(NPh)(NPr(i)(2))(2)](–), which was structurally characterized with the [K(crypt-2.2.2)](+) counterion. The “Cr–N 1-...

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Detalles Bibliográficos
Autores principales: Beaumier, Evan P., Billow, Brennan S., Singh, Amrendra K., Biros, Shannon M., Odom, Aaron L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477034/
https://www.ncbi.nlm.nih.gov/pubmed/28660023
http://dx.doi.org/10.1039/c5sc04608d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477034/
https://www.ncbi.nlm.nih.gov/pubmed/28660023
http://dx.doi.org/10.1039/c5sc04608d

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