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A complex with nitrogen single, double, and triple bonds to the same chromium atom: synthesis, structure, and reactivity
A nitrogen-based analogue of the Schrock and Clark “yl-ene-yne” complex, W(CBu(t))(CHBu(t))(CH(2)Bu(t))(dmpe), has been prepared. The new complex is the nitrido, imido, amido anion [NCr(NPh)(NPr(i)(2))(2)](–), which was structurally characterized with the [K(crypt-2.2.2)](+) counterion. The “Cr–N 1-...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477034/ https://www.ncbi.nlm.nih.gov/pubmed/28660023 http://dx.doi.org/10.1039/c5sc04608d |