Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex

A rhodium complex based on the bis-phosphine carbazolide pincer ligand was investigated in the context of alkane dehydrogenation and in comparison with its iridium analogue. (carb-PNP)RhH(2) was found to catalyze cyclooctane/t-butylethylene (COA/TBE) transfer dehydrogenation with a turnover frequenc...

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Detalles Bibliográficos
Autores principales: Bézier, David, Guan, Changjian, Krogh-Jespersen, Karsten, Goldman, Alan S., Brookhart, Maurice
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477040/
https://www.ncbi.nlm.nih.gov/pubmed/28660029
http://dx.doi.org/10.1039/c5sc04794c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477040/
https://www.ncbi.nlm.nih.gov/pubmed/28660029
http://dx.doi.org/10.1039/c5sc04794c

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