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Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex
A rhodium complex based on the bis-phosphine carbazolide pincer ligand was investigated in the context of alkane dehydrogenation and in comparison with its iridium analogue. (carb-PNP)RhH(2) was found to catalyze cyclooctane/t-butylethylene (COA/TBE) transfer dehydrogenation with a turnover frequenc...
Autores principales: | Bézier, David, Guan, Changjian, Krogh-Jespersen, Karsten, Goldman, Alan S., Brookhart, Maurice |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477040/ https://www.ncbi.nlm.nih.gov/pubmed/28660029 http://dx.doi.org/10.1039/c5sc04794c |
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