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Bond fission in monocationic frameworks: diverse fragmentation pathways for phosphinophosphonium cations
A series of phosphinophosphonium cations ([R(2)PPMe(3)](+); R = Me, Et, (i)Pr, (t)Bu, Cy, Ph and N(i)Pr(2)) have been prepared and examined by collision-induced dissociation (CID) to determine the fragmentation pathways accessible to these prototypical catena-phosphorus cations in the gas-phase. Exp...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477047/ https://www.ncbi.nlm.nih.gov/pubmed/28660025 http://dx.doi.org/10.1039/c5sc03804a |