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Bond fission in monocationic frameworks: diverse fragmentation pathways for phosphinophosphonium cations

A series of phosphinophosphonium cations ([R(2)PPMe(3)](+); R = Me, Et, (i)Pr, (t)Bu, Cy, Ph and N(i)Pr(2)) have been prepared and examined by collision-induced dissociation (CID) to determine the fragmentation pathways accessible to these prototypical catena-phosphorus cations in the gas-phase. Exp...

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Detalles Bibliográficos
Autores principales: Bamford, Karlee L., Chitnis, Saurabh S., Stoddard, Rhonda L., McIndoe, J. Scott, Burford, Neil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477047/
https://www.ncbi.nlm.nih.gov/pubmed/28660025
http://dx.doi.org/10.1039/c5sc03804a