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Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V(15)Sb(6)}-type polyoxovanadates

Antimonato polyoxovanadate (POV) cluster compounds {M(en)(3)}(3)[V(15)Sb(6)O(42)(H(2)O)(x)]·nH(2)O (M = Fe(II), Co(II), Ni(II) and x = 0 or 1) obtained under solvothermal conditions exhibit unusual high water solubility making these compounds promising synthons for generation of new POV structure ty...

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Detalles Bibliográficos
Autores principales: Wendt, Michael, Warzok, Ulrike, Näther, Christian, van Leusen, Jan, Kögerler, Paul, Schalley, Christoph A., Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477048/
https://www.ncbi.nlm.nih.gov/pubmed/28660041
http://dx.doi.org/10.1039/c5sc04571a