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Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V(15)Sb(6)}-type polyoxovanadates
Antimonato polyoxovanadate (POV) cluster compounds {M(en)(3)}(3)[V(15)Sb(6)O(42)(H(2)O)(x)]·nH(2)O (M = Fe(II), Co(II), Ni(II) and x = 0 or 1) obtained under solvothermal conditions exhibit unusual high water solubility making these compounds promising synthons for generation of new POV structure ty...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477048/ https://www.ncbi.nlm.nih.gov/pubmed/28660041 http://dx.doi.org/10.1039/c5sc04571a |