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Chiral hemicucurbit[8]uril as an anion receptor: selectivity to size, shape and charge distribution

A novel eight-membered macrocycle of the hemicucurbit[n]uril family, chiral (all-R)-cyclohexanohemicucurbit[8]uril (cycHC[8]) binds anions in a purely protic solvent with remarkable selectivity. The cycHC[8] portals open and close to fully encapsulate anions in a 1 : 1 ratio, resembling a molecular...

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Detalles Bibliográficos
Autores principales: Kaabel, Sandra, Adamson, Jasper, Topić, Filip, Kiesilä, Anniina, Kalenius, Elina, Öeren, Mario, Reimund, Mart, Prigorchenko, Elena, Lõokene, Aivar, Reich, Hans J., Rissanen, Kari, Aav, Riina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477839/
https://www.ncbi.nlm.nih.gov/pubmed/28694954
http://dx.doi.org/10.1039/c6sc05058a