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Palladium-Catalyzed α-Stereoselective O-Glycosylation of O(3)-Acylated Glycals
[Image: see text] Pd(MeCN)(2)Cl(2) enables the α-stereoselective catalytic synthesis of 2,3-unsaturated O-glycosides from O(3)-acylated glycals without the requirement for additives to preactivate either donor or nucleophile. Mechanistic studies suggest that, unlike traditional (η3-allyl)palladium-m...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5479629/ https://www.ncbi.nlm.nih.gov/pubmed/28514163 http://dx.doi.org/10.1021/acs.orglett.7b01092 |