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Palladium-Catalyzed α-Stereoselective O-Glycosylation of O(3)-Acylated Glycals

[Image: see text] Pd(MeCN)(2)Cl(2) enables the α-stereoselective catalytic synthesis of 2,3-unsaturated O-glycosides from O(3)-acylated glycals without the requirement for additives to preactivate either donor or nucleophile. Mechanistic studies suggest that, unlike traditional (η3-allyl)palladium-m...

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Detalles Bibliográficos
Autores principales:	Sau, Abhijit, Galan, M. Carmen
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2017
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5479629/ https://www.ncbi.nlm.nih.gov/pubmed/28514163 http://dx.doi.org/10.1021/acs.orglett.7b01092

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