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CH(2) Linkage Effects on the Reactivity of Bis(aminophosphine)–Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols
A novel ruthenium complex binding to two subtly different aminophosphine ligands, (o-PPh(2)C(6)H(4)CH(2)NH(2))(o-PPh(2)C(6)H(4)NH(2))RuCl(2), was successfully isolated. This bis(aminophosphine)–ruthenium complex shows efficient activity in both dimethyl oxalate (DMO) and methyl benzoate (MB) hydroge...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5479805/ https://www.ncbi.nlm.nih.gov/pubmed/28638062 http://dx.doi.org/10.1038/s41598-017-04362-9 |