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CH(2) Linkage Effects on the Reactivity of Bis(aminophosphine)–Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols

A novel ruthenium complex binding to two subtly different aminophosphine ligands, (o-PPh(2)C(6)H(4)CH(2)NH(2))(o-PPh(2)C(6)H(4)NH(2))RuCl(2), was successfully isolated. This bis(aminophosphine)–ruthenium complex shows efficient activity in both dimethyl oxalate (DMO) and methyl benzoate (MB) hydroge...

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Detalles Bibliográficos
Autores principales: Fang, Xiaolong, Sun, Mingjun, Zheng, Jianwei, Li, Bin, Ye, Linmin, Wang, Xiaoping, Cao, Zexing, Zhu, Hongping, Yuan, Youzhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5479805/
https://www.ncbi.nlm.nih.gov/pubmed/28638062
http://dx.doi.org/10.1038/s41598-017-04362-9